Ecological significance of alkaline phosphatase activity and phosphatase-hydrolyzed phosphorus in the northern part of Gamak Bay, Korea   总被引：1，自引：0，他引：1  

Kwon HK  Oh SJ  Yang HS 《Marine pollution bulletin》2011,62(11):2476-2482

We investigated the ecological significance of alkaline phsophatase (APase) and alkaline phosphatase-hydrolyzable phosphorus (APHP) in the northern part of Gamak Bay, Korea. APase activity was detectable throughout the year, and dissolved inorganic phosphorus (DIP) concentration and APase activity are highly correlated and can be regarded as an indicator of DIP-limiting conditions. Also, a strong linear positive correlation between APase activity and Chl a concentration indicated that the major part of APase activity may have been induced by phytoplanktons. The APHP proportion in dissolved organic phosphorus (DOP) was above ca. 30% from winter to spring and below ca. 15% from summer to autumn due to freshwater discharge and uptake by phytoplankton. APHP may play an important role in species competition in coastal area such as northern part of Gamak Bay where DIP is limiting. Thus, APase induction by phytoplanktons may be ecologically significant, allowing dominance by these organisms under DIP-limiting conditions.  相似文献   

植物样品中无机元素分析的样品前处理方法和测定技术   总被引：11，自引：5，他引：6  

刘亚轩  李晓静  白金峰  马娜  张勤 《岩矿测试》2013,32(5):681-693

植物样品中无机元素的分析测定在环境地球化学和生物地球化学的研究中起着重要作用。植物样品中元素含量一般较低,须选用科学合理的前处理技术和灵敏度高、精密度好、检出限低的测定方法。本文针对植物样品前处理方法和无机元素分析测定技术的研究进展、优势与不足进行评述。前处理方法主要根据样品和待测元素的性质进行选择:干法灰化所用试剂少、空白值低,但组织致密型的样品不易灰化完全、高温下易造成元素挥发损失;湿法消解样品消解较为完全,但试剂消耗大、空白值高、操作繁琐;微波消解可以防止部分易挥发元素损失,用酸量少、消解速度快,但称样量相对较小,不适于需要大称样量的样品分析。几乎所有针对元素分析的仪器分析技术都可以用于植物样品分析,主要根据仪器适用的元素、必要的干扰校正以及基体改进等方面进行选择:电感耦合等离子体质谱法可同时测定植物样品中40种以上的元素,高分辨质谱的检出限可达fg/mL;电感耦合等离子体发射光谱法适用于某些植物样品中含量较高的P、K、Na等元素的测定;原子吸收光谱法可分析元素达70余种,是普及程度最高的仪器分析技术之一;原子荧光光谱法与氢化物发生技术的联用,在元素含量较低的植物样品分析中技术优势更加明显;新兴的激光诱导击穿光谱技术已被应用于植物样品分析,无需复杂的样品前处理,操作简单快速,可实现原位、在线、实时、多元素同时检测;其他选择性强、灵敏度高的分析技术,满足了一些特定元素不能用常规分析技术测定的需求。当前主流分析技术的样品前处理方法都存在着缺陷,固体进样技术将成为植物样品分析领域的发展方向之一。  相似文献   

中国石油地质学创新发展论评     

崔永强  于晶  王丽丽 《化工矿产地质》2013,(4):242-247,254

石油地质学是国家石油战略的组成部分,是国家石油安全的组成部分,必须予以高度重视。石油地质学来源于实践。但随着石油勘探开发实践的不断深入,仅仅依靠归纳和总结来自实践的认识已经无法满足人们对石油地质学在科学层面的理解和掌握。从沉积层获得的有关构造、生油、储层方面的知识无法全面解释在结晶基底和火山岩中发育油气藏的事实,而最新揭示出金属、非金属矿床、油气藏与深部构造和深部流体存在密切关系,为我们发展石油地质学提供了崭新的思路。欧洲惠更斯号探测器发现土卫六上存在甲烷湖的事实告诉我们,石油地质学的不仅仅是地质学问题,更是天文学问题。所以,及时吸收消化各学科最新成果,创新发展中国石油地质学,已是保障国家石油安全的当务之急。  相似文献   

Association of phosphate with rhyolite glass in marine Neogene tuffs from Patagonia,Argentina     

Nora Rubinstein  Ana M. Fazio  Roberto A. Scasso  Steven Carey 《Sedimentology》2013,60(4):1007-1016

The precipitation/replacement of Ca‐phosphate is a complex process that commonly takes place during the early diagenesis in marine sediments. The unusual occurrence of shallow marine, early diagenetic phosphatic deposits associated with glassy tuffs in the Neogene Gaiman Formation, in the Chubut Province, Patagonia, Argentina, constitutes a good case example for the study of replacement and precipitation of Ca‐phosphate on an unstable substrate. Isocon diagrams illustrate that chemical changes during glass diagenesis include gains in loss on ignition and Ca, and losses of K. These changes are the result of glass hydration during sea water–glass interaction, together with adsorption and diffusion of ions into the bulk shard; combined, these represent an incipient process of volcanic glass replacement by Ca‐phosphate. Subsequent early diagenetic P enrichment in the pore solutions led to phosphate precipitation, associated with pitting on the glass shards and pumice. The associated development of a reactive surface promoted the incorporation of P and Ca into their margins. Lastly, precipitation of calcium phosphate filled the vesicles and other open cavities, inhibiting further glass dissolution. The high porosity and reactivity of the volcanic glass provided an appropriate substrate for phosphate precipitation, leading to the development of authigenic apatite concretions in the volcanic‐glass bearing strata of the Gaiman Formation. This research is of significance for those concerned with marine phosphatic deposits and sheds light on the processes of early diagenetic phosphate precipitation by replacement of an atypical, unstable substrate like hydrated volcanic glass.  相似文献   

萃取法制取磷酸二氢钾工艺研究   总被引：2，自引：0，他引：2       下载免费PDF全文

肖学英  孟瑞英  宋明礼 《盐湖研究》1999,7(3):36-41

本文研究改进了萃取法制取磷酸二氢钾的工艺路线,确定了较适宜的工艺条件,萃取在常温下进行,一次反应得到磷酸二氢钾。产品纯度高,能耗低,有望成为大规模工业生产该产品最经济的路线之一。  相似文献   

孔道结构化合物(H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]的钒氧化态与热稳定性关系研究   总被引：1，自引：0，他引：1  

杨赞中  廖立兵 《地学前缘》2005,12(1):182-187

热处理脱除有机模板易导致VPO体系孔道结构化合物结构破坏,从而阻碍此类材料的实际应用。以孔道结构化合物(H3NCH2CH2NH3)3[(VO)4 (PO4 )2 (HPO4 )4 ](简称V2P3 en)为研究对象,利用热分析(DSC TG)、动态原位高温X 射线衍射(XRD)及多功能X 射线光电子能谱(XPS)等方法,研究了该化合物在不同气氛热处理过程中模板脱除及结构演化规律,重点探讨了钒氧化态的变化对结构稳定性的影响。结果表明,加热过程中随着有机模板的分解脱除,形成较强的还原环境,骨架中的部分钒被还原(V4+→V3+),使原有的配位环境([VⅣO5]三角双锥、[VⅣO6]畸变八面体)与钒的氧化态不符而导致结构重组。因此,钒氧化态的变化是影响热稳定性的重要因素之一。  相似文献   

The contribution of agricultural and urban activities to inorganic carbon fluxes within temperate watersheds   总被引：8，自引：0，他引：8  

Rebecca T. Barnes  Peter A. Raymond 《Chemical Geology》2009,266(3-4):327-336

The lateral transport of bicarbonate as dissolved inorganic carbon (DIC) to the oceans is an integral component of the global carbon budget and can represent the sequestration of CO₂ from the atmosphere. Recently studies have implicated land use change, in particular agricultural development, as an accelerator of bicarbonate export. However, due to the co-variation of land use, bedrock and surficial geologies, and the relationship between bicarbonate export and climate, the impact of anthropogenic activities on DIC export remains an important research question. In order to examine the land use controls on DIC export from small temperate watersheds we sampled 19 streams draining catchments of varying land uses with similar bedrock and surficial geologies. In addition to an agricultural effect, there was a strong correlation between the percent of watershed in urban development and DIC concentrations and DIC yields. Urban watersheds exported 7.8 times more DIC than their nearby forested counterparts and 2.0 times more DIC than nearby agricultural catchments. Isotopic data suggest that excess DIC export from altered systems results from increased chemical weathering, enhanced CO₂ production within urban green spaces, and as a result of organic matter loading from septic systems and leaky sewer lines. Furthermore, we found that nitrogen additions (e.g. fertilizers and manure) are aiding in the dissolution of lime, increasing the total export of DIC from agricultural watersheds. Calculated anthropogenic loading rates ranged from 0.43 to 0.86 mol C m^− 2 yr^− 1. These loading rates suggest that a significant portion of global DIC export might be attributable to human activities, although the impacts on CO₂ sequestration are difficult to determine.  相似文献   

云南白登浅海相磷块岩与青龙哨陆相磷块岩的对比研究     

贺瑾瑞  朱杰勇  周健  洪建磊  李侃  熊亮 《地质与资源》2009,18(4):292-297

白登磷矿是我国重要的浅海相磷块岩矿床,而青龙哨磷矿是我国重要的陆相磷块岩矿床.两地磷矿品位高,储量大,是滇池地区正在开采的2个重要磷矿基地.野外工作研究发现,青龙哨角砾状磷块岩顶板的磷锶铝石矿层和高岭土黏土岩二者呈超覆式不整合接触.深入研究发现其具有陆相磷块岩的许多特征,而没有浅海相磷块岩的原生沉积构造特征.同时,白登磷矿见上下2层工业矿体,而青龙哨磷矿仅见1层工业矿体.对此二矿床特点进行了对比分析.  相似文献   

贵州瓮福磷矿床含磷岩系沉积层序的划分     

李守能  程鹏林 《贵州地质》2005,22(1):26-30

应用层序地层学的概念和方法,从沉积特征研究入手,对该区的含磷岩系——洋水组划分出5个沉积层序(旋回),结合层序界面及层序的归纳描述,确定了层序类型,并认为洋水组是一套海进体系域中由一系列低级别退积型沉积层序(旋回)组成的高级层序(Ⅰ级))。  相似文献   

贵州开阳地区富磷矿成矿作用过程与找矿潜力          下载免费PDF全文

刘建中  王泽鹏  杜远生  陈国勇  张亚冠  吴文明  王大福  谭代卫  李松涛  唐嗣刚  付芝康  万大学  向群  杨妮娅  汪小勇  李磊  唐铸  宋威方  苏成鹏 《贵州地质》2019,36(1):10-17

贵州开阳地区是我国富磷矿集中分布区。近年来,通过产学研协同创新、联合攻关,实现了磷矿理论创新,推动了该区磷矿找矿突破;厘清了开阳地区磷矿成矿受黔中古陆长期剥蚀夷平的平缓海岸型的无障壁海滩(缓坡浅滩)环境控制;建立了富磷矿"三阶段"动态磷矿成矿模式,阐明了"富"的成矿作用过程,即原始生物-化学、波浪波选(机械)暴露淋滤、磷质沉淀胶结成矿作用。建立新的磷矿区域成矿模式和地质找矿预测模型,开展找矿预测,通过工程验证,估算磷矿资源量(333+334?) 54892万吨,取得了富磷矿找矿新的重大突破。预测区内富磷矿还有8亿吨的找矿潜力。  相似文献